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Pretty Polycyclic Pictures/ Links
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Pretty Polycyclic Pictures/ Links

UV spectral patterns for a PAH series
uvpatterns.jpg

A few from John Fetzer's PAH research 

A Polarized light spectral pattern
polarized.jpg

The large PAHs in a carbon black extract
carbonblakpahs.jpg

These and many other pictures appear in The Chemistry and Analysis of the Large (C>=24C) Polycyclic Aromatic Hydrocarbons (Wiley-Interscience, 2000).
 
Questions
Why are large PAHs important?
Answer: It was long thought that the large PAHs were either not found in samples or of little biological impact. With work done in the past decade, both have been shown to be false. Large PAHs are ubiquitous, but were not found before because they were not looked for or the methods used were optimized for the small PAHs.
What are the differences in the analysis of larger PAHs that require other approaches than for the smaller ones?
Answer: As the number of ring carbon number goes up, the number of isomers goes up exponentially. The relative difference between isomers also gets proportionally smaller. Separating and identifying specific PAHs gets more difficult.

The International Society for Polycyclic Aromatic Compounds (ISPAC)

Need large PAH standards? Contact Chiron AS!

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